The Kelvin is defined setting the fixed numerical value of the Boltsmann constant k to 1.380649*10^-23 J*K^-1, (J=kg*m^2*s^-2), given the definition of the kilogram, the meter, and the second.
The amount of substance of 6.02214076*10^23 elementary entities. This number is the fixed numerical value of the Avogadro constant NA ,when expressed in the unit mol^-1